Section 19 - Carboxylic Acids
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Carboxylic Acids - Section 19 of Organic Chemistry Notes is 7 pages in length (page 19-1 through page 19-7) and covers ALL you'll need to know on the following lecture/book topics:
19-1 -- Nomenclature of Carboxylic Acids
· Common Names of Carboxylic Acids
· Diacids
· Systematic Names of Carboxylic Acids (IUPAC)
· Dioic Acids
19-3 -- Spectroscopy of Carboxylic Acids
· IR and 1H NMR
· D2O Exchange
19-3 -- Polarity of Carboxylic Acids
· Why are Smaller Carboxylic Acids Water-Soluble?
· Hydrogen Bonding
· Carboxylate Salts and Water Solubility
19-4 -- Acidity of Carboxylic Acids
· The Acid Dissociation Reaction
· Effect of Electronegative Substituents on Acidity
19-5 -- Preparation of Carboxylic Acids
· Via Oxidation of Aromatic Compounds Containing Benzylic Hydrogens
· Via Oxidation of Alcohols or Aldehydes
· Via Grignard Reagent (R-MgX) + CO2
· Via Nitrile (R-CΞN:) Hydrolysis
19-6 -- Reactions of Carboxylic Acids
· Reduction with Lithium Aluminum Hydride (LiAlH4)
· The Hunsdieker Reaction and its Detailed Mechanism (Involves Radicals)
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