Section 8 - Stereochemistry of Organic Compounds
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Stereochemistry of Organic Compounds: A Detailed Look - Section 8 of Organic Chemistry Notes is 16 pages in length (page 6-1 through page 6-16) and covers ALL you'll need to know on the following lecture/book topics:
8-1 -- Definitions
· Chiral, Achiral, Enantiomers, and Stereogenic Centers
· Internal Mirror Planes
8-2 -- Enantiomers
· Interactions of Enantiomers with Other Reactants (ex. Acylose)
· Rotation of Plane-Polarized Light
· Angle of Rotation
· Dextrorotatory (D) or (+) vs. Levorotatory (L) or (-)
· Absolute Configurations “R” and “S”
· Racemic Mixtures and Racemates
8-4 -- Specifying Absolute Configurations
· How to Determine “R” and “S” Enantiomers
· Cyclic Permutations
8-5 -- Compounds with Multiple Stereocenters
· Diastereomers
· Meso Compounds and Planes of Symmetry
8-6 -- Cyclic Compounds
8-7 -- Isomer Types – A Summary
8-8 -- Fischer Projections
8-9 -- Manipulating Fischer Projections
· Allowed Operations
· 180° Rotation (Allowed)
· Cyclic Permutations of 3 Substituents (Allowed)
· Forbidden Operations
· Swapping only 2 Substituents (Forbidden)
· 90° Rotation in the Plane (Forbidden)
8-10 -- Organic Reactions – Stereochemical Considerations
· Achiral Reactants
· Diastereomers
· Optically Active (Chiral) Reactants
8-15 -- Conformational Enantiomers
· Chair Conformations and Enantiomeric Cyclohexanes
· Racemates of Substituted Cyclohexane Products
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