Section 5 - Structure and Reactivity of Alkenes
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Structure and Reactivity of Alkenes - Section 5 of Organic Chemistry Notes is 14 pages in length (page 5-1 through page 5-14) and covers ALL you'll need to know on the following lecture/book topics:
5-1 -- Alkenes (“Olefins”)
· Strength of a Double Bond (d.b) Relative to a Single Bond (s.b)
5-1 -- Stereoisomerism of Alkenes (Cis/Trans)
5-1 -- Nomenclature of Alkenes
· 6 Rules for Naming Alkenes
· Numbering the Principal Chain (Main Chain)
· Identifying Locator #’s for Double Bonds
· Endings / Suffixes (-ene, -diene, -triene, and –tetraene)
5-3 -- Naming Branched Alkenes
· Alkenyl Substituents (Alkenes as Branches)
5-4 -- Naming Alkenes that Exhibit Stereoisomerism
· E-Configurations and Z-Configurations (E/Z Stereochemistry)
· Priority System within Nomenclature (E/Z Stereochemistry)
5-7 -- Relative Stabilities of Alkenes
· Trans-Alkenes vs. Cis-Alkenes
· Cyclic Alkenes
· Alkyl Group Substitution (Branches) Stabilize Alkenes
5-8 -- Electrophilic Addition Reactions
· Electrophilic Addition of HX (X = -Cl, -Br, -I)
· Regiospecific Reactions
5-9 -- Markovnikov's Rule
· Carbocation Stability
· Hyperconjugaton and Electron Delocalization
· Resonance Picture of Carbocations
5-11 -- The Hammond Postulate
5-12 -- Rearrangement of Carbocations
· 1,2-Hydride Shifts (:H-)
· 1,2-Alkyl Shifts (:R-)
5-13 -- Degree of Unsaturation
· Calculating the Degree of Unsaturation
· General Formula for Degree of Unsaturation
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