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Section 4 - The Study of Organic Reactions: An Overview

The Study of Organic Reactions: An Overview - Section 4 of Organic Chemistry Notes is 14 pages in length (page 4-1 through 4-14) and covers ALL you'll need to know on the following lecture/book topics:

SECTION 4 – The Study of Organic Reactions: An Overview

4-1 -- Types of Organic Reactions
  · Addition Reactions (A + B --> C)
  · Elimination Reactions (A --> B + C)
  · Substitution Reactions (A + B --> C + D)
  · Rearrangement Reactions (A --> B)
4-2 -- Reaction Mechanisms
  · Use of “Arrow-Pushing”
  · Heterolytic Bond Breaking and Heterogenic Bond Forming
  · Homolytic Bond Breaking and Homogenic Bond Forming
4-4 -- Polar Reactions and How They Occur
  · Electron-Rich (δ-) Sites of a Molecule
  · Electron-Poor (δ+) Sites of a Molecule
  · Nucleophiles and Electrophiles
  · Mechanisms for Polar Reactions
4-6 -- Radical Reactions and How They Occur
  · Free Radical Reactions
  · Mechanisms for Radical Reactions (Chain Reactions)
  · Initiation, Propagation, and Termination Steps
4-8 -- Thermodynamics of Organic Reactions
  · Equilibrium Expressions
  · Standard Free-Energy Changes (ΔG°)
  · Bond Dissociation Energies (BDE)
  · Table of BDE Values
4-10 -- Kinetics of Organic Reactions
  · Energy Diagrams and Transition States
  · Activation Energies (Ea), Reaction Rates, and Rate Laws
  · Multi-Step Reactions and Their Mechanisms
  · Reaction Intermediates
  · The Rate-Limiting Step (“Rate-Determining Step”)
  · First-Order Reactions vs. Second-Order Reactions (More Rate Laws)

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