Section 4 - The Study of Organic Reactions: An Overview
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The Study of Organic Reactions: An Overview - Section 4 of Organic Chemistry Notes is 14 pages in length (page 4-1 through 4-14) and covers ALL you'll need to know on the following lecture/book topics:
4-1 -- Types of Organic Reactions
· Addition Reactions (A + B --> C)
· Elimination Reactions (A --> B + C)
· Substitution Reactions (A + B --> C + D)
· Rearrangement Reactions (A --> B)
4-2 -- Reaction Mechanisms
· Use of “Arrow-Pushing”
· Heterolytic Bond Breaking and Heterogenic Bond Forming
· Homolytic Bond Breaking and Homogenic Bond Forming
4-4 -- Polar Reactions and How They Occur
· Electron-Rich (δ-) Sites of a Molecule
· Electron-Poor (δ+) Sites of a Molecule
· Nucleophiles and Electrophiles
· Mechanisms for Polar Reactions
4-6 -- Radical Reactions and How They Occur
· Free Radical Reactions
· Mechanisms for Radical Reactions (Chain Reactions)
· Initiation, Propagation, and Termination Steps
4-8 -- Thermodynamics of Organic Reactions
· Equilibrium Expressions
· Standard Free-Energy Changes (ΔG°)
· Bond Dissociation Energies (BDE)
· Table of BDE Values
4-10 -- Kinetics of Organic Reactions
· Energy Diagrams and Transition States
· Activation Energies (Ea), Reaction Rates, and Rate Laws
· Multi-Step Reactions and Their Mechanisms
· Reaction Intermediates
· The Rate-Limiting Step (“Rate-Determining Step”)
· First-Order Reactions vs. Second-Order Reactions (More Rate Laws)
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