Section 9 - Alkyl Halides (R-X)
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The Chemistry of Alkyl Halides - Section 9 of Organic Chemistry Notes is 10 pages in length (page 9-1 through page 9-10) and covers ALL you'll need to know on the following lecture/book topics:
SECTION 9 – Alkyl Halides ( R-X)
9-1 -- Preparation of Alkyl Halides from Alkanes
· Chlorination Reaction (Cl2) - Unselective
· Bromination Reaction (Br2) – Much More Selective
9-1 -- Why is Bromination Easier to Control than Chlorination?
· Radical Stabilization
· Thermochemistry of Bromination and Chlorination Reactions
· Analysis of Transition States
9-4 -- Allylic Hydrogens
· Resonance-Stabilization of the Allylic Radical
· Allylic Bromination and the Use of NBR
· Reactants that Produce 2 Types of Allylic Radicals
9-6 -- Benzylic Hydrogens
· Low Bond Dissociation Energy (BDE)
· Most Favorable Resonance Structure Preserves the Aromatic Ring
· Benzyl Radicals
9-7 -- Preparation of Alkyl Halides from Alcohols
· Via the Addition of HX
· Via the Use of Thionyl Chloride (SOCl2) in Pyridine Solvent
· Via the Use of Phosphorus Tribromide (PBr3)
9-8 -- Organometallic Compounds
· Carbon-Metal Bonds (Organometallics)
· Carbanions
· Grignard Reagents
· Organolithium Reagents (the Alkyllithium Reagent)
· Organocopper Reagents (the Lithium Dialkyl Copper Reagent)
9-10 -- Various Ways to Form New C-C Bonds
· Formation of New C-C Single Bonds (σ-bonds)
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